By Chin Pao Huang, Charles R. O'Melia, James J. Morgan
Offers accomplished experimental and theoretical analyses of chemical reactions in multiphase, multispecies structures. Explores the foundations and purposes of floor chemistry, soil chemistry, microbiology, geochemistry, redox response, and colloid chemistry to environmental platforms. Examines the impact of abiotic and biotic interfaces on chemical reactions in aquatic atmosphere platforms. contains chapters via Werner Stumm, the founding father of aquatic chemistry.
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Extra resources for Aquatic chemistry: interfacial and interspecies processes
Acta 1986,50, 1847-1860. 22. Blum, A. ; Lasaga, A. C. ; Wiley Interscience: New York, 1987; pp 255-292. 23. Stumm, W; Wollast, R. Rev. Geophys. 1990, 28/1, 53-69. 24. ; Stumm, W Langmuir 1991, 7, 809--813. 25. Sulzberger, B. Chemistry of the Solid-Water Interface; Wiley Interscience: New York, 1992; Chapter 10. 26. Lakind, J. ; Stone, A. T. Geochim. Cosmochim. Acta 1989,53, 961-971. 27. ; Stumm, W. Langmuir 1992, 8, 1671. 28. Plummer, L. ; Wigley, T. M. ; Parkhurst, D. L. Am. J. Sci. 1978,278, 179-216.
References 1. Stumm, W. Chemistry of the Solid-Water lnteiface; Wiley Interscience: New York, 1992. 2. Sposito, G. The Suiface Chemistry of Soils; Oxford University: New York, 1984. 3. Sposito, G. The Chemistry of Soils; Oxford University: New York, 1989. 4. Schindler, P. ; Wiley Interscience: New York, 1987; pp 83-110. 5. Dzombak, D. ; Morel, F. M. M. Suiface Complexation Modeling; Hydrous Ferric Oxide; Wiley Interscience: New York, 1990. 6. ; Stumm, W Colloids Surf 1981,2, 101-117. 7. Smith, R.
Part a: The ligandcatalyzed dissolution reaction of a M2 0 3 can be described by three elementary 51eps: A fast ligand adsorption step (equilibrium); a slow detachment process; and fast protonation subsequent to detachment, restoring the inCipient surface configuration. Part b: The dissolution rate increases with increasing oxalate concentrations. Part c: In accord with the reaction scheme of (a) and of eq lla, the rate of ligand-catalyzed dissolution of 8-AIP3 by the ligands, R1• (nrrwllm2 per hour) can be interpreted as linearly dependent on the surface concentrations of the complexes CL '.