By John Comyn
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It is only used for making expensive products such as aircraft and racing cars. Rinsing in tap water, rather than deionized or distilled water gives more durable joints. A recommended procedure for mild steel is as follows: Remove rust or millscale by brushing. Vapour degrease. Grit-blast. Etch in 4% solution of hydrofluoric acid at room temperature for 10 min. Rinse immediately in tap water. Immediately remove smut (carbon) in a bath composed of chromium trioxide 100g, concentrated sulfuric acid 57 ml and water to make 1 1 at 70 "C.
The inhibitors are applied from aqueous solution and act as hydration inhibitors by bonding to the surface by P-0-A1 bonds. At low concentration (about 1 ppm) only one phosphate group of the N T M P molecule is attached to the metal oxide, but all three are attached at 1OOOppm. A single molecular layer of NTMP gives the maximum improvement in durability. Because of its physical properties and ease of moulding, polypropylene is used to make car bumpers. The low surface-energy of the untreated polymer makes painting impossible, but a primer based on chlorinated polypropylene in organic solvents adheres to polypropylene with some interdiffusion.
Two-part silicones, which are essential for thick sections, normally contain water and are catalyzed with stannous octoate for a fast cure, or dibutyltindilaurate for a slower cure. Silicone adhesives are soft and compliant, and have good chemical and environmental resistance. Joints with silicones can operate over a wide temperature range, from about - 60 to 200 "C. The glass transition temperature is - 120 "C but because of their regular structure crystallization can occur at - 60 "C. POLYURETHANES Polyurethane adhesives are made by reacting a low molecular weight polymer containing at least two OH end groups with a diioscyanate.